【醫學百科●Reppe合成法】
本帖最後由 楊籍富 於 2013-1-13 19:18 編輯 <br /><br /><P align=center><STRONG><FONT size=5>【<FONT color=red>醫學百科●Reppe合成法</FONT>】</FONT></STRONG></P><P><STRONG></STRONG> </P>
<P><STRONG>拼音</STRONG></P>
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<P><STRONG>Reppehéchéngfǎ<BR><BR>烯烴或炔烴、CO與一個親核試劑如H2O,ROH,RNH2，RSH，RCOOH等在均相催化劑作用下形成羰基酸及其衍生物。</STRONG></P>
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<P><STRONG>許多過渡金屬如Ni,Co,Fe,Rh,Ru,Pd等的鹽和絡合物均可作催化劑。</STRONG></P>
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<P><STRONG>反應過程首先形成酰基金屬，然后和水、醇、胺等發生溶劑解反應形成酸、酯、酰胺：</STRONG></P>
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<P><STRONG>參考文獻</STRONG></P>
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<P><STRONG>J.W.CopenhaverandM.H.Bigelow,AcetyleneandCarbonMonoxideChemistry,NewYork,1949,p246.W.Reppe,AcetyleneChemistryU.S.Dept.CommercePB,1949,18852-S.Kirk-Othmer,EncyclopediaofChemicalTechnology,NewYork,1953,11648.H.Kroper,MethodenderorganischenChemie4/11,1955,413.D.W.F.Hardie,AcetyleneMasfactllrealtdUses,NewYork,1965,p67.L.F.FieserandM.Fieser,ReagentsforOrganicSynthesis,NewYork,1967,p61,183,185,190,519,720,722,723.</STRONG></P>
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<P><STRONG>引用：<A href="http://big5.wiki8.com/Reppehechengfa_120351/" target=_blank>http://big5.wiki8.com/Reppehechengfa_120351/</A></STRONG></P>
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